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61.
A geological and geochemical study has been carried out to investigate the relationships between major mud volcano structures and deep fluid migration in the Cheleken peninsula, in the South Caspian Basin. The fluid geochemistry allowed the origin and migration of the saline waters and the hydrocarbons to be deduced along with the regional source and reservoir rocks. The emitted waters formed by the mixing of deep highly saline water from the main source rocks of the Maykop Fm with the Caspian-like pore water contained in the Pliocene reservoirs. The water composition is very similar to that emitted by the mud volcanoes in Azerbaijan, allowing comparisons to be done between the reservoirs in the western and eastern sides of the South Caspian Basin. The associated oil is derived from a mixed type II/III kerogen deposited in a sub-oxic marine environment and generated during the early oil window. The oil biomarkers indicate that the source rock is the Maykop Fm., as previously determined for the other areas of the South Caspian Basin.The spontaneous emissions, showing different morphologies, are mainly aligned along normal and transtensive fault systems, which provide effective pathways for rapid fluid ascent from deep reservoirs to the surface.  相似文献   
62.
Remotely and accurately quantifying the canopy nitrogen status in crops is essential for regional studies of N budgets and N balances. In this study, we optimised three-band spectral algorithms to estimate the N status of winter wheat. This study extends previous work to optimise the band combinations further and identifies the optimised central bands and suitable bandwidths of the three-band nitrogen planar domain index (NPDI) for estimating the aerial N uptake, N concentration and aboveground biomass. Analysis of the influence of bandwidth change on the accuracy of estimating the canopy N status and aboveground biomass indicated that the suitable bandwidths for optimised central bands were 37 nm at 846 nm, 13 nm at 738 nm and 57 nm at 560 nm for assessing the aerial N uptake and were 37 nm at 958 nm, 21 nm at 696 nm and 73 nm at 578 nm for the assessment of the aerial N concentration and were 49 nm at 806 nm, 17 nm at 738 nm and 57 nm at 560 nm for the estimation of aboveground biomass. The optimised three-band NPDI could consistently and stably estimate the aerial N uptake and aboveground biomass of winter wheat in the vegetative stage and the aerial N concentration in the reproductive stage compared to the fixed band combinations. With suitable bandwidths, the broadband NPDI demonstrated excellent performance in estimating the aerial N concentration, N uptake and biomass. We conclude that the band-optimised algorithm represents a promising tool to measure the improved performance of the NPDI in estimating the aerial N uptake and biomass in the vegetative stage and the aerial N concentration in the reproductive stage, which will be useful for designing improved nitrogen diagnosis systems and for enhancing the applications of ground- and satellite-based sensors.  相似文献   
63.
The retreat of the Tethys Sea and the uplift of the Tibetan Plateau play the critical roles in driving Asian climatic changes during the Cenozoic. In the Pamir–Tien Shan convergence zone, over 3000 m of Cenozoic successions, consisting of marine deposits in the lower, continental clay and fine sand in the middle, and molasse in the upper part, record the evolution of the Tethys Sea, the Asian aridification, and the deformation of the Pamir. In this work, the existing biostratigraphic subdivisions and new electronic spinning resonance dating results were used to assign ages to formations within the Ulugqat section. Sedimentary facies analysis and multi-proxy indices were used to reconstruct the paleo-environmental evolution. The results show: (1) the Pamir–Tien Shan convergence zone has undergone progressive environmental changes from shallow marine before ∼34 Ma to arid land at ∼23 Ma and finally to inter-mountain basin by ∼5.3 Ma; (2) the overall increase in mean size of grains, decrease in redness, in magnetic susceptibility, and in proportion of the ultrafine component of the sediments studied revealed a long-term strengthening in potential energy to transporting medium, cooling, and enhanced continental aridity, respectively; (3) the easternmost edge of the Tethys Sea prevailed in the western Tarim Basin from late Cretaceous to early Cenozoic, and finally retreated from this region around the Eocene–Oligocene transition, which in turn strengthened the Asian aridification; (4) accumulation of molasse with an upper age of ∼1 Ma suggests that the deformation front of the Pamir migrated to this area at or before that time.  相似文献   
64.
The origin of perylene, a five-ring polycyclic aromatic hydrocarbon (PAH), in sediments has been a matter of constant debate and its formation mechanisms remain unclear. A perylene record in sediment was described and could support a clear link between perylene and terrigenous organic matter (OM) input. The distributions of PAHs, the variations of organic proxies such as the ratio of terrigenous to aquatic n-alkanes (TAR(HC)) and 5α(H)-stanols/Δ5-sterols ratio in sediments have been investigated. Sediments were sampled from a pond artificially created during the Middle Ages from a swampy area. In the period prior to the pond creation, for which high contributions of terrigenous OM were evidenced, perylene was found to be the predominant PAH. Furthermore, perylene content was shown to increase in response to the establishment of more reducing conditions. This result supports the common idea that the main source of perylene is natural and derives from biogenic precursors under reducing conditions. The creation of the pond in this wetland is marked by the deposition of a wood rich level characterized both by more oxygenated conditions and higher concentrations of perylene. These high concentrations could result from the introduction of high concentrations of biogenic precursors of perylene under oxidative conditions. Subsequently, the progressive burial of the woody level could have allowed the establishment of oxygen depleted conditions and the formation of perylene. These results validate the use of perylene as a paleoenvironmental marker of terrigenous sources but it must be carefully used as a marker for syn- or post-depositional oxygen depleted conditions in lacustrine environments.  相似文献   
65.
Marginal seas provide a globally important interface between land and interior ocean where organic carbon is metabolized, buried or exported. The trophic status of these seas varies seasonally, depending on river flow, primary production, the proportion of dissolved to particulate organic carbon and other factors. In the Strait of Georgia, about 80% of the organic carbon in the water column is dissolved. Organic carbon enters at the surface, with river discharge and primary production, particularly during spring and summer. The amount of organic carbon passing through the Strait (∼16 × 108 kg C yr−1) is almost twice the standing inventory (∼9.4 × 108 kg C). The organic carbon that is oxidized within the Strait (∼5.6 × 108 kg yr−1) presumably supports microbial food webs or participates in chemical or photochemical reactions, while that which is exported (7.2 × 108 kg yr−1) represents a local source of organic carbon to the open ocean.  相似文献   
66.
A laboratory experiment was performed with the clam Ruditapes decussatus, fed with the toxic dinoflagellate Gymnodinium catenatum and the non-toxic algae Isochrysis galbana (14 days) and subsequently only with I. galbana (15 days). Individual paralytic shellfish toxins were determined by LC-FLD in G. catenatum cells, whole clam tissues, and particulate organic matter (POM) produced by clams. The toxins dcSTX and dcGTX2 + 3 in the algae were less abundant than C1 + 2 and B1, but were predominant in clams during both the exposure and depuration phases. The toxin dcNEO was only detected in clams during a short period, indicating conversion from other compounds. The toxin composition of the POM indicated the export of dcSTX as faeces or pseudo-faeces along the entire experiment (2.5–14 nmol mg−1), B1 was present in a short period of the exposure and C1 + 2 and dcGTX2 + 3 absent. A mass balance calculation indicated that approximately 95% of C1 + 2 and 85% of B1 supplied to the clams were converted into other toxins or lost in solution. Conversely, the net gain of 512, 61 and 31 nmol for dcSTX, dcGTX2 + 3 and dcNEO, respectively, suggests the conversion from other assimilated compounds by clams during exposure and depuration phases.  相似文献   
67.
Ultraviolet-B (UV-B) radiation (0.5, 1.0, 1.5, and 3.0 W m?2) induced higher H2O2 production and lipid peroxidation in alga Gelidium amansii inhabiting in lower subtidal regions than upper subtidal alga Ptercladiella capillacea. Compared to G. amansii, mycosporine-like amino acid (MAA) concentration in P. capillacea was higher and can be increased by 0.5–1.0 W m?2 UV-B, while carotenoid concentration was lower but also increased by 1.5–3.0 W m?2 UV-B. UV-B increased ascorbate concentration, but to a higher degree in P. capillacea. UV-B decreased glutathione concentration, but to a higher degree in G. amansii. UV-B increased ascorbate peroxidase (APX) and glutathione reductase (GR) activities in P. capillacea but decreased them in G. amansii. UV-B increased superoxide dismutase and catalase activities, but to a higher degree in G. amansii. So, G. amansii suffered greater oxidative stress from UV-B radiation. P. capillacea can effectively reduce UV-B sensitivity by increasing sunscreen ability and antioxidant defense capacity.  相似文献   
68.
Off the western coast of Sumatra among the islands of Pulau Banyak, fishing is the primary occupation for the men of Haloban. They are self-described “traditional” fishers, using low-tech gear and small boats to catch fish, octopus, lobster, and other sealife in the nearby coral reefs and mangroves. Women also regularly venture out into the deep mud of the mangroves to collect clams. Their efforts to extract livelihoods and subsistence from the reefs take place in an open-access commons with few formal institutions or enforcement mechanisms to regulate resource use. While explicit regulations and customary limitations on fishing in the coral reef commons are lacking, Haloban fishers improvise some common etiquette and practices that are adaptable to the shifting context.This case study presents Haloban fishers' use of the commons as situated practices, unarticulated and embedded within a complex social–ecological system. These practices reflect fishers' understanding of, and relationship with, their environment, and may represent a nascent form of local “rules-in-use”, informing behavior without direct social mechanisms for enforcement. This paper presents research collected using ethnographic methods, including participant observation at sea. As NGOs and government agencies work to craft management plans that share use of the reefs with tourism and conservation, a better understanding of actual resource use and fishing practice may inform more nuanced, adaptable, and truly “local” community-based management.  相似文献   
69.
Chabahar Bay in SE of Iran is a shallow semi-enclosed environment affected by anthropogenic activities. In this paper, 19 sediment samples were collected and concentration of selected metals (Cu, Pb, Zn, Cd, Ni, Cr, Co, V and Fe) was determined using ICP-MS analytical method. Sediment samples from five stations were also selected for sequential extraction analysis and concentration of metals in each fraction was determined using ICP-OES. In order to investigate the environmental quality of Chabahar Bay, geographic information system (GIS) along with geochemical data, environmental indices and statistical analyses were used. Calculated contamination degree (Cd) revealed that most contaminated stations (Ch3, S1 and S3) are located SE of Chabahar Bay and contamination decreases in a NW direction. The S9 station, west of the bay, is also contaminated. High organic matter (OM) content in the sediments is most likely the result of fuel and sewage discharge from fishing vessels along with discharge of fishing leftovers. Significant correlation coefficient among OM, Fe, Cu, Pb, Zn and Cd seemingly reflects the importance of the role that OM and Fe oxy-hydroxides play in the metals mobility. The results of hierarchical cluster analysis (HCA), computed correlation coefficient and sequential extraction analysis suggest that Cu, Pb, Zn and Cd probably come from antifouling and sea vessel paints, while Ni, Cr, Co, V and Fe are most likely contributed by ophiolitic formations located north of the bay and/or deep sea sediments. Average individual contamination factors (ICFs) indicated that the highest health hazard from the bay is posed by Cu, Pb and Zn.  相似文献   
70.
利用20年(1992-2012年)的ECCO2模式模拟数据,主要研究了东印度洋(EIO)水体输运的季节变化.在EIO选取3个断面,分别为赤道、80°E和6°N.研究结果表明,跨赤道和80°E的季节输运主体部分大致相补偿.跨赤道的大部分水体输运局限在上层100 m,80°E的水体输运具有复杂结构,与显著的季风流、Wyrtki Jets(WJs)、赤道潜流(EUC)等有关.6°N上层水体净输运较小,但存在较强的边界流和相对较弱的内区流.纬向流的显著变化发生在80°E.在季风盛行季节,由于WJs减弱,赤道附近的水体输运以西向的梯度流为主,上层100 m的其余区域则主要受季风流控制.同样,由于EUC减弱,西向的梯度流与次表层东向的EUC之间也存在转换.在季风转换季节,季风流减弱,WJs与EUC分别在上层100 m和次表层占主导地位.此外,本研究还讨论了与季风流、WJs和EUC相关的盐水和暖水交换,有助于了解研究区域内温度和盐度的水平和垂直结构.  相似文献   
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